Electron Affinity Trend

   most atoms release energy when they gain an electron
      this is defined to be a negative electron affinity

    but some atoms require energy
      this is defined to be a positive electron affinity

energy is sometimes required due to:
      1. opening a new sublevel
      2. breaking a half-filled sublevel


Example 1. Which atom would have a positive electron affinity, sodium or magnesium?

      Na is 1s22s22p63s1 - the new electron would fill in the 3s orbital
      Mg is 1s22s22p63s2 - the new electron would open the 3p sublevel

      magnesium has a positive electron affinity --
        it is difficult to open a new sublevel


Example 2. Which atom would have a positive electron affinity, nitrogen or oxygen?

      N is 1s22s22p3 - the new electron would enter the 3p sublevel
      O is 1s22s22p4- the new electron would also enter the 3p sublevel

      nitrogen has a positive electron affinity --
        the p sublevel was half-filled with 3 electrons


most atoms have negative electron affinities - they release energy
some atoms predictably have positive electron affinities - they require energy

     but there are NO CLEAR TRENDS
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Slide 13 of 14