Electron Affinity Trend
most atoms release energy when they gain an electron
this is defined to be a negative electron affinity
but some atoms require energy
this is defined to be a positive electron affinity
energy is sometimes required due to:
1. opening a new sublevel
2. breaking a half-filled sublevel
Example 1. Which atom would have a positive electron affinity, sodium or magnesium?
Na is 1s22s22p63s1 - the new electron would fill in the 3s orbital
Mg is 1s22s22p63s2 - the new electron would open the 3p sublevel
magnesium has a positive electron affinity --
it is difficult to open a new sublevel
Example 2. Which atom would have a positive electron affinity, nitrogen or oxygen?
N is 1s22s22p3 - the new electron would enter the 3p sublevel
O is 1s22s22p4- the new electron would also enter the 3p sublevel
nitrogen has a positive electron affinity --
the p sublevel was half-filled with 3 electrons
most atoms have negative electron affinities - they release energy
some atoms predictably have positive electron affinities - they require energy
but there are NO CLEAR TRENDS
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